Jacques Lemaître
Nationalité: Belge
Expertise
Physico-chimie des surfaces et colloides.
Thermochimie des solutions aqueuses: calculs de solubilité de composés inorganiques (phosphates, carbonates, oxalates...).
Chimie et solubilité des phosphates ce calcium en milieux aqueux.
Synthèse de phosphates de calcium, en particulier l'hydroxyapatite; biominéralisation.
Biomatériaux de comblement osseux : bio-ciments phospho-calciques injectables, biocéramiques.
Méthodologie expérimentale : plans statistiques d'expérience, en particulier dans le domaine des biomatériaux (planification d'expériences in vitro et in vivo).
Expertise
Physico-chimie des surfaces et colloides.
Thermochimie des solutions aqueuses: calculs de solubilité de composés inorganiques (phosphates, carbonates, oxalates...).
Chimie et solubilité des phosphates ce calcium en milieux aqueux.
Synthèse de phosphates de calcium, en particulier l'hydroxyapatite; biominéralisation.
Biomatériaux de comblement osseux : bio-ciments phospho-calciques injectables, biocéramiques.
Méthodologie expérimentale : plans statistiques d'expérience, en particulier dans le domaine des biomatériaux (planification d'expériences in vitro et in vivo).
Mission
Suppléant du professeur H. Hofmann à la direction du Laboratoire de Technologie des Poudres.
Responsable du groupe de recherche "Chimie de Surface et Biomatériaux".
Responsable de plusieurs enseignements:
- Science des matériaux divisés (physico-chimie aux interfaces)
– Thermodynamique des matériaux (responsabilité partagée avec MM H. Hofmann et P. Bowen)
- Biomatériaux (matériaux pour usage biomédical)
- Matériaux biomimétiques
- Optimisation des matériaux et plans d'expériences (méthodologie expérimentale).
Au sein de la Section Science et Génie des Matériaux, coordinateur de la filière "Matériaux pour applications biologiques et médicales".
Precipitation of Nanosized and Nanostructured Powders: Process Intensification and Scale-Out Using a Segmented Flow Tubular Reactor (SFTR)
Chemical Engineering Technology. 2011. DOI : 10.1002/ceat.201000324.Control of morphology and nanostructure of copper and cobalt oxalates: Effect of complexing ions, polymeric additives and molecular weight
The Royal Society of Chemistry. 2010. DOI : 10.1039/c0nr00420k.Contribution of Aggregation to the Growth Mechanism of Seeded Calcium Carbonate Precipitation in the Presence of Polyacrylic Acid
American Chemical Society. 2010. DOI : 10.1021/jp103787p.A thermodynamic solution model for calcium carbonate: Towards an understanding of multi-equilibria precipitation pathways
Journal of Colloid and Interface Science. 2009. DOI : 10.1016/j.jcis.2009.09.005.P-31 Solid-State NMR Study of the Chemical Setting Process of a Dual-Paste Injectable Brushite Cements
Journal Of Biomedical Materials Research Part B-Applied Biomaterials. 2009. DOI : 10.1002/jbm.b.31372.Preparation and characterization of dense nanohydroxyapatite/PLLA composites
Material Science and Engineering C. 2009. DOI : 10.1016/j.msec.2008.06.005.Can bioactivity be tested in vitro with SBF solution ?
Biomaterials. 2009. DOI : 10.1016/j.biomaterials.2009.01.008.Bone substitute: Transforming beta-tricalcium phosphate porous scaffolds into monetite
Biomaterials. 2008. DOI : 10.1016/j.biomaterials.2008.04.041.Precipitation of Nanostructured Copper Oxalate: Substructure and Growth Mechanism
Journal of Physical Chemistry B. 2006. DOI : 10.1021/jp0606816.A thermodynamic model for the precipitation of nanostructured copper oxalates
Journal of Crystal Growth. 2006. DOI : 10.1016/j.jcrysgro.2005.11.085.Investigation of nucleation and crystal growth kinetics of nickel manganese oxalates
Journal of Crystal Growth. 2005. DOI : 10.1016/j.jcrysgro.2005.02.032.Evidence of a transient phase during the hydrolysis of a calcium-deficient hydroxyapatite
Zeitschrift für Metallkunde. 2005. DOI : 10.3139/146.018135.Use of seeds to control precipitation of calcium carbonate and determination of seed nature
Langmuir. 2005. DOI : 10.1021/la048525i.Process and reactor for the manufacture of powders of inhalable medicaments
US8496944 ; CA2502502 ; JP5172075 ; AT551993 ; EP1585585 ; US2009068275 ; JP2006504746 ; EP1585585 ; US2004197275 ; WO2004034943 ; AU2003267433 ; AU2003267433 ; CA2502502 ; WO2004034943 . 2004.Immediate implant placement using injectable calcium phosphate hydraulic cement in dogs
Journal of Applied Biomaterials & Biomechanics. 2004. DOI : 10.1177/228080000400200204.Vieillissement des biociments brushitiques
Lausanne, EPFL, 2004. DOI : 10.5075/epfl-thesis-2916.Précipitation Contrôlée de carbonate de calcium en Présence de germes: mécanisme de précipitation
2004. 4 éme Colloque Science et Technologie des Poudres "3 jours pour faire parler la poudre", Compiègne, May, 4-6, 2004. p. 12p.High quality nickel manganese oxalate powders synthetized in a new segmented flow tubular reactor
Solid State Ionics. 2004. DOI : 10.1016/S0167-2738(03)00282-0.Assembly of nano-domain buidings blocks of copper oxalate with a cubic morphology
2004. p. L1.4.1-L.1.4.7. DOI : 10.1557/PROC-788-L1.4.Pasty or liquid multiple constituent compositions for injectable calcium phosphate cements
ES2545256 ; EP1443981 ; CA2463742 ; US7407542 ; US2004244651 ; EP1443981 ; CA2463742 ; WO03041753 . 2003.Injectable calcium phosphate hydraulic cement (CPHC) used for periodontal tissue regeneration: A study of a dog model
Journal of Applied Biomaterials & Biomechanics. 2003. DOI : 10.1177/228080000300100305.Raman microspectrometry studies of calcified tissues and related biomaterials
Dental and Medical Problems. 2003.Influence of polymeric additives on the biological properties of brushite cements: an experimental study in rabbit
Journal of Biomedical Materials Research Part A. 2003. DOI : 10.1002/jbm.a.10539.Hydroxyapatite cement scaffolds with controlled macroporosity: fabrication and mechanical properties
Biomaterials. 2003. DOI : 10.1016/S0142-9612(02)00406-4.High quality manganite powders synthesised with a new reactor technology
2003. p. 567-574.Development of a continuous segmented flow tubular reactor and the " scale-out" concept - In search of perfect powders
Chemical Engineering & Technology. 2003. DOI : 10.1002/ceat.200390046.Précipitation de CaCO3 en réacteur tubulaire
Lausanne, EPFL, 2002. DOI : 10.5075/epfl-thesis-2623.Development and characterisation of injectable calcium phosphate cements for use in vertebroplasty
Lausanne, EPFL, 2002. DOI : 10.5075/epfl-thesis-2509.The biodegradation mechanism of calcium phosphate biomaterials in bone
Journal of Biomedical Materials Research :(+ suppl Applied Biomaterials Section). 2002.Radio-opacité d'un ciment phospho-calcique pour la vertébroplastie
Actualités en biomatériaux; 2002. p. 79-85.Les ciments hydrauliques phosphocalciques: formulations et propriétés
Actualités en biomatériaux; 2002. p. 15-22.Interdisciplinary research conference on biomaterials
Journal of Biomedical Materials Research. 2002. DOI : 10.1002/jbm.10348.Influence of raw powder granulometry on the mechanical properties of a calcium phosphate bone cement
2002. p. 1555-1558. DOI : 10.4028/www.scientific.net/KEM.206-213.1555.Bone colonization of beta-TCP granules incorporated in brushite cements
Journal of Biomedical Materials Research :(+ suppl. Applied Biomaterials section). 2002. DOI : 10.1002/jbm.10262.Précipitation d'oxalates métalliques nanostructurés
2001. p. 19-24.Nano-Composites Powders, A New Concept for their Synthesis
Scripta Materialia. 2001. DOI : 10.1016/S1359-6462(01)00903-4.Mechanical Characterisation of Brushite and Hydroxyapatite Cements
Biomaterials. 2001. DOI : 10.1016/S0142-9612(01)00041-2.Precipitation of self-organized copper oxalate polycrystalline particles in the presence of hydroxymethylcellulose (HPMC): control of morphology
Journal of Colloid and Interface Science. 2000. DOI : 10.1006/jcis.2000.6747.New morphology of calcium oxalate trihydrate precipitated in a segmented flow tubular reactor
Journal of Materials Science Letters. 2000. DOI : 10.1023/A:1006771428827.Mechanical characterization of brushite cements: a Mohr circles'approach
Journal of Biomedical Materials Research :(+ suppl Applied Biomaterials Section). 2000.Low temperature aqueous synthesis (LTAS) of BaTiO3: a statistical design of experiment approach
Journal of the European Ceramic Society. 2000. DOI : 10.1016/S0955-2219(99)00150-8.In vitro aging of a calcium phosphate cement
Journal of Materials Science: Materials in Medicine. 2000. DOI : 10.1023/A:1008927624493.Hydraulic calcium phosphate cements for bone reconstruction: from crystal chemistry to biomechanics
Revue de chirurgie orthopédique et réparatrice de l'appareil moteur. 2000.Effect of several additives and their admixtures on the physico-chemical properties of a calcium phosphate cement
Journal of Materials Science: Materials in Medicine. 2000. DOI : 10.1023/A:1008997118576.Control of gentamicin release from a calcium phosphate cement by admixed poly(acrilic acid)
Journal of Pharmaceutical Sciences. 2000. DOI : 10.1002/1520-6017(200010)89:10<1262::AID-JPS4>3.0.CO;2-7.Calcium carbonate precipitation using new segmented flow tubular reactor
AIChE Journal. 2000. DOI : 10.1002/aic.690460616.Calcination and morphological evolution of cubic copper oxalate particles
Journal of Materials Science Letters. 2000. DOI : 10.1023/A:1006711724828.Evidence of a transient phase during the hydrolysis of calcium-deficient hydroxyapatite
International Journal Of Materials Research. 2022. DOI : 10.3139/ijmr-2005-0090.Rapid evaluation of bioactive Ti-based surfaces using an in vitro titration method
Nature Communications. 2019. DOI : 10.1038/s41467-019-09673-1.Calcium phosphate formation on titanium-based surfaces: bioactivity evaluated by in vitro methods
Lausanne, EPFL, 2018. DOI : 10.5075/epfl-thesis-8874.A comparative study of simulated body fluids in the presence of proteins
Acta Biomaterialia. 2017. DOI : 10.1016/j.actbio.2017.02.006.Degradation rates and products of pure magnesium exposed to different aqueous media under physiological conditions
BioNanoMaterials. 2016. DOI : 10.1515/bnm-2015-0020.Evaluation de la bioactivité des substituts osseux
2013Precipitation of Nanosized and Nanostructured Powders: Process Intensification and Scale-Out Using a Segmented Flow Tubular Reactor (SFTR)
Chemical Engineering Technology. 2011. DOI : 10.1002/ceat.201000324.Control of morphology and nanostructure of copper and cobalt oxalates: Effect of complexing ions, polymeric additives and molecular weight
The Royal Society of Chemistry. 2010. DOI : 10.1039/c0nr00420k.Contribution of Aggregation to the Growth Mechanism of Seeded Calcium Carbonate Precipitation in the Presence of Polyacrylic Acid
American Chemical Society. 2010. DOI : 10.1021/jp103787p.A thermodynamic solution model for calcium carbonate: Towards an understanding of multi-equilibria precipitation pathways
Journal of Colloid and Interface Science. 2009. DOI : 10.1016/j.jcis.2009.09.005.Can bioactivity be tested in vitro with SBF solution ?
Biomaterials. 2009. DOI : 10.1016/j.biomaterials.2009.01.008.Preparation and characterization of dense nanohydroxyapatite/PLLA composites
Material Science and Engineering C. 2009. DOI : 10.1016/j.msec.2008.06.005.A thermodynamic model for the precipitation of nanostructured copper oxalates
Journal of Crystal Growth. 2006. DOI : 10.1016/j.jcrysgro.2005.11.085.Precipitation of Nanostructured Copper Oxalate: Substructure and Growth Mechanism
The Journal of Physical Chemistry B. 2006. DOI : 10.1021/jp0606816.Use of seeds to control precipitation of calcium carbonate and determination of seed nature
Langmuir. 2005. DOI : 10.1021/la048525i.Evidence of a transient phase during the hydrolysis of a calcium-deficient hydroxyapatite
Zeitschrift für Metallkunde. 2005. DOI : 10.3139/146.018135.Investigation of nucleation and crystal growth kinetics of nickel manganese oxalates
Journal of Crystal Growth. 2005. DOI : 10.1016/j.jcrysgro.2005.02.032.Immediate implant placement using injectable calcium phosphate hydraulic cement in dogs
Journal of Applied Biomaterials & Biomechanics. 2004. DOI : 10.1177/228080000400200204.Précipitation Contrôlée de carbonate de calcium en Présence de germes: mécanisme de précipitation
2004. 4 éme Colloque Science et Technologie des Poudres "3 jours pour faire parler la poudre", Compiègne, May, 4-6, 2004.Vieillissement des biociments brushitiques : étude expérimentale "in vitro" et simulations numériques
Lausanne, EPFL, 2004. DOI : 10.5075/epfl-thesis-2916.Assembly of nano-domain buidings blocks of copper oxalate with a cubic morphology
2004. p. L1.4.1 - L.1.4.7. DOI : 10.1557/PROC-788-L1.4.High quality nickel manganese oxalate powders synthetized in a new segmented flow tubular reactor
Solid State Ionics. 2004. DOI : 10.1016/S0167-2738(03)00282-0.Development of a continuous segmented flow tubular reactor and the " scale-out" concept - In search of perfect powders
Chemical Engineering & Technology. 2003. DOI : 10.1002/ceat.200390046.Influence of polymeric additives on the biological properties of brushite cements: an experimental study in rabbit
Journal of Biomedical Materials Research Part A. 2003. DOI : 10.1002/jbm.a.10539.High quality manganite powders synthesised with a new reactor technology
2003. p. 567 - 574.Raman microspectrometry studies of calcified tissues and related biomaterials
Dental and Medical Problems. 2003.Injectable calcium phosphate hydraulic cement (CPHC) used for periodontal tissue regeneration: A study of a dog model
Journal of Applied Biomaterials & Biomechanics. 2003. DOI : 10.1177/228080000300100305.Hydroxyapatite cement scaffolds with controlled macroporosity: fabrication and mechanical properties
Biomaterials. 2003. DOI : 10.1016/S0142-9612(02)00406-4.Les ciments hydrauliques phosphocalciques: formulations et propriétés
Actualités en biomatériaux; 2002. p. 15 - 22.Development and characterisation of injectable calcium phosphate cements for use in vertebroplasty
Lausanne, EPFL, 2002. DOI : 10.5075/epfl-thesis-2509.Interdisciplinary research conference on biomaterials
Journal of Biomedical Materials Research. 2002. DOI : 10.1002/jbm.10348.Radio-opacité d'un ciment phospho-calcique pour la vertébroplastie
Actualités en biomatériaux; 2002. p. 79 - 85.Influence of raw powder granulometry on the mechanical properties of a calcium phosphate bone cement
2002. p. 1555 - 1558. DOI : 10.4028/www.scientific.net/KEM.206-213.1555.Bone colonization of beta-TCP granules incorporated in brushite cements
Journal of Biomedical Materials Research :(+ suppl. Applied Biomaterials section). 2002. DOI : 10.1002/jbm.10262.The biodegradation mechanism of calcium phosphate biomaterials in bone
Journal of Biomedical Materials Research :(+ suppl Applied Biomaterials Section). 2002.Précipitation de CaCO3 en réacteur tubulaire : rôle des germes pour le contrôle de la granulométrie et de la sélectivité
Lausanne, EPFL, 2002. DOI : 10.5075/epfl-thesis-2623.Précipitation d'oxalates métalliques nanostructurés
2001. p. 19 - 24.Nano-Composites Powders, A New Concept for their Synthesis
Scripta Materialia. 2001. DOI : 10.1016/S1359-6462(01)00903-4.Mechanical Characterisation of Brushite and Hydroxyapatite Cements
Biomaterials. 2001. DOI : 10.1016/S0142-9612(01)00041-2.New morphology of calcium oxalate trihydrate precipitated in a segmented flow tubular reactor
Journal of Materials Science Letters. 2000. DOI : 10.1023/A:1006771428827.Effect of several additives and their admixtures on the physico-chemical properties of a calcium phosphate cement
Journal of Materials Science: Materials in Medicine. 2000. DOI : 10.1023/A:1008997118576.Control of gentamicin release from a calcium phosphate cement by admixed poly(acrilic acid)
Journal of Pharmaceutical Sciences. 2000. DOI : 10.1002/1520-6017(200010)89:10<1262::AID-JPS4>3.0.CO;2-7.Calcination and morphological evolution of cubic copper oxalate particles
Journal of Materials Science Letters. 2000. DOI : 10.1023/A:1006711724828.In vitro aging of a calcium phosphate cement
Journal of Materials Science: Materials in Medicine. 2000. DOI : 10.1023/A:1008927624493.Calcium carbonate precipitation using new segmented flow tubular reactor
AIChE Journal. 2000. DOI : 10.1002/aic.690460616.Low temperature aqueous synthesis (LTAS) of BaTiO3: a statistical design of experiment approach
Journal of the European Ceramic Society. 2000. DOI : 10.1016/S0955-2219(99)00150-8.Hydraulic calcium phosphate cements for bone reconstruction: from crystal chemistry to biomechanics
Revue de chirurgie orthopédique et réparatrice de l'appareil moteur. 2000.Mechanical characterization of brushite cements: a Mohr circles'approach
Journal of Biomedical Materials Research :(+ suppl Applied Biomaterials Section). 2000.Precipitation of self-organized copper oxalate polycrystalline particles in the presence of hydroxymethylcellulose (HPMC): control of morphology
Journal of Colloid and Interface Science. 2000. DOI : 10.1006/jcis.2000.6747.Qualitative and quantitative investigation of calcium phosphate of biological interest by raman microspectrometry
Recent Research Developments in Applied Spectroscopy. 1999.Better control of nucleation and phase purity using a new segmented flow tubular reactor: Model system: Precipitation of calcium oxalate
1999.Implants osseux
DE60033025 ; DE60033025 ; EP1178847 ; US6905516 ; EP1178847 ; AU4283800 ; WO0071178 . 1999.Reinforcement of osteosynthesis screws with brushite cements
Bone. 1999. DOI : 10.1016/S8756-3282(99)00142-8.Raman microspectrometry studies on brushite cement: in vivo evolution in a sheep model
Bone. 1999. DOI : 10.1016/S8756-3282(99)00139-8.Volume effect on biological properties of a calcium phosphate hydraulic cement: experimental study in sheep
Bone. 1999. DOI : 10.1016/S8756-3282(99)00147-7.Histological and Biomechanical Studies of Two Bones Colonizable Cements in Rabbits
Bone. 1999. DOI : 10.1016/S8756-3282(99)00131-3.Aqueous synthesis of mixed yttrium-barium oxalates
Chemistry of Materials. 1999. DOI : 10.1021/cm980745s.Adsorption of catalase on hydroxyapatite
Journal of colloid and interface science. 1998. DOI : 10.1006/jcis.1998.5759.Contrôle de la composition, de la morphologie et de la granulométrie des oxalates de Y, Ba et Cu précipités en milieu aqueux
Lausanne, EPFL, 1998. DOI : 10.5075/epfl-thesis-1846.Evaluation des propriétés biologiques in vivo chez le lapin d'un ciment hydraulique phospho-calcique.
Actualités en Biomatériaux; 1998. p. 203 - 208.Synthesis of nickel hydroxide powders by urea decomposition
Journal of the European Ceramic Society. 1998. DOI : 10.1016/S0955-2219(98)00034-X.Biomechanical characterization of a biodegradable calcium phosphate hydraulic cement : A comparison with porous biphasic calcium phosphate ceramics
Journal of Biomedical Materials Research :(+ suppl Applied Biomaterials section). 1998.Development of the new segmented flow tubular reactor for powder technology
1998.Développement d'un modèle permettant de tester des substituts osseux injectables et mise au point d'un ciment phosphocalcique de comblement
Bulletin de l'Académie nationale de médecine. 1998.Influence d'un additif polymérique sur la morphologie de particules d'oxalate de cuivre
1998. p. 53 - 54.Gentamicin sulfate release from a hydraulic calcium phosphate cement : Influence of the additive poly(acrylic acid).
1997. p. 1009 - 1010.Synthesis, sintering and expansion of Al0.8Mg0.6Ti1.6O5 : A low-thermal-expansion material resistant to thermal decomposition
Journal of Materials Science. 1997. DOI : 10.1023/A:1018611311015.Adsorption of succinylated lysozyme on hydroxyapatite
Journal of Colloid and Interface Science. 1997. DOI : 10.1006/jcis.1997.4787.Optimization of setting time and mechanical strength of beta-TCP/MCPM cements
1997. p. 477 - 480.Gentamicin-loaded hydraulic calcium phosphate bone cement as antibiotic delivery system
Journal of Pharmaceutical Sciences. 1997. DOI : 10.1021/js960405a.Kinetics of dissolution of beta-tricalcium phosphate
Journal of Colloid and Interface Science. 1997. DOI : 10.1006/jcis.1997.4846.Densification and anomalous grain growth during sintering of undoped barium titanate
Journal of the American Ceramic Society. 1997. DOI : 10.1111/j.1151-2916.1997.tb02949.x.Composition effects on the pH of a hydraulic calcium phosphate cement
Journal of Materials Science : Materials in Medicine. 1997. DOI : 10.1023/A:1018583706335.Hydraulic Surgical Cement
DE69803398 ; ES2170533 ; US6425949 ; PT1023032 ; DK1023032 ; DE69803398 ; AT211379 ; EP1023032 ; JP2001518359 ; EP1023032 ; CA2306562 ; WO9917710 . 1997.New Injectable Composites for Bone Replacement
Seminars in Musculoskeletal Radiology. 1997.Synthesis of beta-tricalcium phosphate powder with controlled specific surface area.
1996. p. 205 - 208.Slip casting of BaTiO3 produced by low-temperature aqueous synthesis
Journal of the European Ceramic Society. 1996. DOI : 10.1016/0955-2219(96)00009-X.Effects of Ca/P atomic ratio on the sinterability and phase purity of b-TCP powders prepared by solid-state reaction.
1996. p. 197 - 200.Synthesis, X-ray diffraction and solid-state 31P magic angle spinning NMR study of a-tricalcium phosphate
Journal of Materials Science: Materials in Medicine. 1996. DOI : 10.1007/BF00122016.Resorption of, and bone formation from, new β‐tricalcium phosphate‐monocalcium phosphate cements: An in vivo study
Journal of Biomedical Materials Research. 1996. DOI : 10.1002/(SICI)1097-4636(199602)30:2<193::AID-JBM9>3.0.CO;2-M.Oxalate precipitation using a new tubular plug flow reactor.
1996. p. 2109 - 2111.Control of the synthesis of alpha-tricalcium orthophosphate by X-ray diffraction and solid-state 31P magic angle spinning NMR
Phosphorus Research Bulletin. 1996.Influence des différentes étapes de la préparation des pièces crues de titanate de baryum sur les profils de raies de diffraction
Silicates Industriels. 1996.Réacteur continu à écoulement segmenté pour la synthèse de poudres minérales par précipitation
US6458335 ; DE69707288 ; DE69707288 ; AT206633 ; EP0912238 ; EP0912238 ; AU4114397 ; WO9802237 . 1996.Effect of beta-TCP granularity on setting time and strength of calcium phosphate hydraulic cement
Journal of Materials Science: Materials in Medicine. 1996. DOI : 10.1007/BF00121187.Effects of sulfate, pyrophosphate, and citrate ions on the physicochemical properties of cements made of beta-tricalcium phosphate-phosphoric acid-water mixtures
Journal of the American Ceramic Society. 1996. DOI : 10.1111/j.1151-2916.1996.tb08746.x.Préparation de suspensions aqueuses de vermiculite pour l'élaboration de films diélectriques
Lausanne, EPFL, 1994. DOI : 10.5075/epfl-thesis-1249.Propriétés physico-chimiques et ostéogéniques d'un biociment hydraulique à base de phosphates de calcium
Lausanne, EPFL, 1993. DOI : 10.5075/epfl-thesis-1171.Enseignement et PhD
A dirigé les thèses EPFL de
Nathalie Jongen, Marcel Donnet, Christian Pittet, Sandrine Gay